摘要
All-inorganic perovskites are rapidly emerging as novel optoelectronic functional materials owing to their flu-orescence properties.However,the stability of these materials has always been the biggest challenge for their applications in photoelectric devices.Therefore,this study focuses on developing phosphor-aluminosilicate-based CsPbX_(3)(X=Cl,Br,and I)glass with a low reaction temperature by adding CsCO_(3),PbX_(2),and NaX to the raw materials in order to improve the stabilities.The glass network intermediates of SiO_(2) and Al_(2)O_(3) doping in the raw material enhanced the stability of the pure phosphate glass network structure and devitrification while decreas-ing the melting temperature.Full chromatographic CsPbX 3 quantum dots(QDs)encapsulated in phosphate-based glass were found to increase the fluorescence properties and quantum efficiency(>59%).Notably,the high water stability of CsPbX_(3) QDs glasses,with the maintenance of 90% luminous intensity,emerged when soaked in water.In addition,the excellent thermal stability and anti-ion exchange properties of the CsPbX_(3) QDs glasses were re-vealed.Benefiting from the above,multicolor light-emitting diode(LED)devices were assembled with a mixture of phosphors of CsPbX_(3) QDs glasses and commercial red-emission K 2 SiF 6:Mn 4+phosphor spread on an InGaN chip,demonstrating bright light with superior luminous properties.Phosphor-aluminosilicate-based CsPbX_(3) QDs glass with high stability and low formation temperature would provide new methods for applications in lighting and displays.
基金
This work was supported in part by the China Postdoctoral Science Foundation(No.2022M711438)'the Natural Science Foundation of Shandong Province(ZR2020ME045 and ZR2020ME046)'the“New Universities 20”Foundation of Jinan(Grant No.2021GXRC099).
