离子液体改性的金属有机框架材料催化CO_(2)与环氧化物环加成反应研究进展

Research progress on ionic liquid modified metal organic framework materials for cycloaddition of CO_(2)and epoxides

离子液体改性的金属有机框架材料(MOFs@IL)作为一种高活性､高稳定性､易分离的新型催化剂在CO_(2)环加成反应研究中逐渐吸引人们的注意。从催化机理､合成策略､性能表现3个方面介绍了MOFs@IL材料在CO_(2)捕获及转化为环状碳酸盐领域最新研究进展,并对未来发展方向进行总结和展望。

Metal organic framework material modified by ionic liquids(MOFs@IL),as a new type of catalyst with high activity,high stability and easy separation,has gradually attracted people's attention in the study of CO_(2)cycloaddition reaction.The latest research progress on the application of MOFs@IL materials in the fields of CO_(2)capture and CO_(2)to cyclic carbonates is introduced from the aspects of catalytic mechanism,synthesis strategy,and performance,and their future development directions are summarized and prospected.