摘要
Spintronics is a cutting-edge field of developing new electronic devices by manipulating the electron spin and magnetic moment[1].Traditional spintronic research mainly focuses on transition metals and inorganic semiconductors,while organic molecules have the advantage of being extremely easy to realize efficient spin control by modifying the specific external conditions for desired electronic structures and magnetic characteristics.Corrole,as a ring-contracted porphyrin,is the aromatic analog of the central macrocycle of vitamin Bi2.Corrole has a squeezed inner cavity and three inner NHs in its free-base form,making it easier to stabilize high-valent metal ions and thus a promising candidate in spintronics.
