摘要
选用Zn、Ga、Sn为金属助剂制备了IrZn/SiO_(2)、IrGa/SiO_(2)和IrSn/SiO_(2)三种双金属催化剂,探讨不同金属助剂对Ir位点结构及催化丙烷脱氢性能影响。结果表明,催化剂中Ir位点的分散性极大影响催化性能。
Three bimetallic catalysts,IrZn/SiO2,IrGa/SiO2,and IrSn/SiO2 modified by different metal promoters(Zn,Ga,and Sn)were used to investigate the effects of different metal promoters on the structure of Ir active sites and propane dehydrogenation performance.A series of results showed that the dispersion of Ir sites significantly affected the catalytic performance.
作者
王明山
马瑞
周博
解晓伟
孙长勇
Wang Mingshan;Ma Rui;Zhou Bo;Xie Xiaowei;Sun Changyong(School of Chemical Engineering and Light Industry,Guang Dong University of Technology,Guangzhou Guangdong 510006,China;Chemistry and Chemical Engineering Guangdong Laboratory,Shantou Guangdong 515031,China)
出处
《山西化工》
CAS
2024年第1期1-2,14,共3页
Shanxi Chemical Industry
基金
国家自然科学基金项目(22102060)
广东省自然科学基金面上项目(2023A1515010971)
化学与精细化工广东省实验室青年人才引进项目(1911023,2111001)。
关键词
双金属催化剂
金属助剂
丙烷脱氢
bimetallic catalysts
promoter metal
propane dehydrogenation