溶液系统中挥发性溶质间化学反应的摩尔吉布斯函数

Molar Gibbs Function for the Chemical Reaction of Volatile Solutes in a Solution System

对于溶液反应系统中挥发性溶质间的化学反应,其Δ_(r)G_(m)^(■)的求算与其他反应系统存在本质的不同。本文对此进行讨论,并建议物理化学教材对此给出说明,以避免可能的应用错误。

For a reaction occurring between volatile solutes in a solution system,the calculation of the Gibbs function is fundamentally different from that of other reaction systems.This paper discusses the calculation of the Gibbs function and suggests that the significant difference in the calculation should be indicated in physical chemistry textbooks to avoid possible errors in teaching and application.