摘要
Rechargeable aqueous zinc-based batteries(RAZBs)are rapidly developing as very promising energy storage devices for both grid-scale and portable applications,thanks to their inherent safety,cost effectiveness,environmental friendliness,and competitive energy density.Increasing efforts have been devoted to alleviating the formidable issues of nonuniform plating/stripping,corrosion,and hydrogen evolution related to zinc anode.Significant progress has been made in reversibility and cyclic stability of RAZBs.However,the problems have yet to be resolved well.In this review,strategies for zinc composition and structure optimization and anode–electrolyte interface construction are summarized.Perspectives for the further development of highperformance zinc anodes for RAZBs are outlined to guide future research and to accelerate their commercialization process.
基金
support from the China Natural Science Foundation(grant nos.21935003 and 22278392)
Strategic Priority Research Program of the CAS(grant no.XDA21070100)
Energy Revolution S&T Program of Yulin Branch,Dalian National Laboratory For Clean Energy,CAS(grant no.DNLYLEC202201)
CAS Strategic Leading Science&Technology Program(A)(grant no.XDA21070000)
Dalian High Level Talent Innovation Support Program(grant no.2020RD05)
Youth Innovation Promotion Association,CAS(grant no.2022184)
DICP funding(grant no.DICPI202136).