MOFs材料在不对称催化中的应用

Application of MOFs in asymmetric catalysis

目前金属-有机框架(MOFs)材料已经在多个领域得到了发展,其中包括气体吸附、催化等方向.近年来,由于不对称催化的快速发展,手性MOFs材料在立体选择性催化中也得到了研究者们的广泛关注.手性MOFs材料具有很强的手性识别能力,并且由于有机配体的可修饰性,使MOFs材料具有更多的活性催化位点.文章详细介绍了手性MOFs材料的分类、合成思路,及其在不对称催化应用中的最新进展.

So far,metal-organic frameworks(MOFs)have been developed in many fields,including gas adsorption,catalysis,and other directions.In recent years,due to the rapid development of asymmetric catalysis,chiral MOFs in stereoselective catalysis has attracted the attention of chemical researchers.Chiral MOFs have strong chiral recognition ability and may have more active catalytic sites due to the modifiability of organic ligands.In this review,the classification and synthesis of chiral MOFs and their application in asymmetric catalysis are introduced in detail.