具有avarane骨架结构的Dysidea属海绵来源的倍半萜醌/氢醌类天然产物的合成研究进展

Research Progress in the Synthesis of Sesquiterpene Quinones and Hydroquinones Natural Products with Avarane Skeleton from Dysidea sp.

将具有avarane骨架结构的Dysidea属海绵来源的倍半萜醌/氢醌类天然产物按照连接醌/氢醌部分和倍半萜部分的键的差异分为三类,并以关键的合成策略为线索,分别对目前已报道的这三类倍半萜醌/氢醌类天然产物的合成方法进行了较为详细的阐述,期望能对其他天然产物的合成研究提供帮助.

Sesquiterpene quinones and hydroquinones obtained from the marine sponge Dysidea sp.with avarane skeleton are classified into three categories based on the differences of the bond connecting the quinone/hydroquinone unit and the sesquiterpene unit.The reported synthetic methods for these three types of natural products are reviewed in detail based on their key synthetic strategies with the aim of assisting in the synthesis of other natural products.