联烯胺化合物的区域选择性双官能团化

Regiocontrollable Difunctionalization of N-Allenamines

联烯胺作为一种富电子联烯类化合物,由于其具有不同的反应位点和较高的活性,近年来受到了广泛的关注.高效可控地实现联烯胺化合物的区域选择性官能团化,可以成功构建多类有价值的分子骨架.主要讨论了近几年来在联烯胺化合物的区域选择性双官能团化领域的研究进展,并详细讨论了多数转化的反应机理.

As an electron-rich diene compound,N-allenamine has received wide spread attention in recent years due to its different reaction sites and high reactivity.Efficient and controllable regioselective functionalization of N-allenamines can successfully construct functionalized molecules.The research progress in the field of regioselective bifunctionalization of N-allenamines in recent years is mainly discussed,and the reaction mechanisms of most conversions in detail are discussed.