摘要
采用无粉尘污染的湿法混炼工艺将溶聚丁苯橡胶(SSBR)和白炭黑制备成湿法混炼胶M-SSBR/SiO_(2),再与顺丁橡胶(BR)通过机械混炼制备成轿车轮胎胎面混炼胶M-SSBR/BR/SiO_(2),并对其进行结构与性能研究。结果表明:与传统机械混炼制备的胎面混炼胶SSBR/BR/SiO_(2)相比,M-SSBR/BR/SiO_(2)的结合胶含量提高27%;并且Payne效应大幅度降低,说明填料分散性显著改善;M-SSBR/BR/SiO_(2)硫化胶的300%定伸模量提高17%,回弹性能提高16%,表征滚动阻力的60℃的tanδ降低24%,压缩生热降低30%。
It is of great significance to develop energy-saving green rubber processing technology and high performance(oil-saving)rubber nanocomposites for high-quality rubber products.In this paper,the solution polymerized styrene-butadiene rubber(SSBR)solution and silica(SiO_(2))suspension were wet-mixed to prepare M-SSBR/SiO_(2) compound without dust pollution.Then,the M-SSBR/BR/SiO_(2) was further obtained by mechanically blending the M-SSBR/SiO_(2) compound with butadiene rubber(BR),and the structure and properties were studied.The bound rubber content of M-SSBR/BR/SiO_(2) compound was 27%higher than that of the SSBR/BR/SiO_(2) compound prepared by traditional mechanical mixing;and the Payne effect of M-SSBR/BR/SiO_(2) compound was greatly weakened,implying significantly improved filler dispersion.In addition,the modulus at 300%and the resilience of M-SSBR/BR/SiO_(2) vulcanizates increased 17%and 16%,respectively;and the tanδ@60℃and heat build-up of M-SSBR/BR/SiO_(2) vulcanizates decreased 24%and 30%,respectively.Therefore,M-SSBR/BR/SiO_(2) tread compound prepared by wet mixing technology showed excellent filler dispersion and comprehensive properties,especially lower rolling resistance and heat build-up,which is an ideal compound for the development of green oil-saving tire.
作者
张传伟
贺爱华
ZHANG Chuanwei;HE Aihua(College of Polymer Science and Engineering,Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization,Key Laboratory of Rubber-Plastics,Ministry of Education,Qingdao University of Science and Technology,Qingdao 266042,China)
出处
《青岛科技大学学报(自然科学版)》
CAS
2024年第2期116-122,共7页
Journal of Qingdao University of Science and Technology:Natural Science Edition
基金
国家重点研发计划项目(2022YFB3704700,2022YFB3704702)
山东省重大科技创新工程项目(2021CXGC010901)
泰山学者工程项目(2022-2026).
关键词
溶聚丁苯橡胶
白炭黑
湿法混炼
滚动阻力
生热
solution polymerized styrene-butadiene rubber
silica
wet mixing method
rolling resistance
heat build-up