摘要
Vanadium-based cathodes have received widespread attention in the field of aqueous zinc-ion batteries,presenting a promising prospect for stationary energy storage applications.However,the rapid capacity decay at low current densities has hampered their development.In particular,capacity stability at low current densities is a requisite in numerous practical applications,typically encompassing peak load regulation of the electricity grid,household energy storage systems,and uninterrupted power supplies.Despite possessing notably high specific capacities,vanadium-based materials exhibit severe instability at low current densities.Moreover,the issue of stabilizing electrode reactions at these densities for vanadium-based materials has been explored insufficiently in existing research.This review aims to investigate the matter of stability in vanadium-based materials at low current densities by concentrating on the mechanisms of capacity fading and optimization strategies.It proposes a comprehensive approach that includes electrolyte optimization,electrode modulation,and electrochemical operational conditions.Finally,we presented several crucial prospects for advancing the practical development of vanadium-based aqueous zinc-ion batteries.
作者
窦欣月
谢雪芳
梁叔
方国赵
Xinyue Dou;Xuefang Xie;Shuquan Liang;Guozhao Fang(School of Materials Science and Engineering,Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan Province,Central South University,Changsha 410083,China;College of Physical Science and Technology,Xinjiang University,Urumqi 830017,China)
基金
supported by the National Natural Science Foundation of China(52072411)
the Scientific Research Program of the Higher Education Institution of Xinjiang(XJEDU2022P001)
the Central South University Innovation-Driven Research Programme(2023CXQD038)
the National Key Research and Development Program of China(2023YFC2908305)。
