摘要
制备了有机-无机-钙钛矿材料(C_(2)H_(7)NPbBr_(3)NCs),并用于修饰玻碳电极。使用该电极研究了Cr^(3+)的电化学行为,同时优化了Cr^(3+)浓度、溶液pH值、缓冲溶液pH值及缓冲溶液用量等实验条件。在Na_(2)HPO_(4)-C(OH)(COOH)(CH_(2)COOH)_(2)(枸橼酸)缓冲溶液(pH=5.60)中,采用循环伏安法发现,在1.0~8.0μmol·L^(-1)浓度范围内,Cr^(3+)的浓度与电流呈线性关系。所制备的修饰电极可直接用于废水中Cr^(3+)的测定,且具有较强抗干扰能力。
The organic-inorganic-perovskite material(C_(2)H_(7)NPbBr_(3)NCs)was prepared and used to modify the glass carbon electrode.By using the electrode,behavior of Cr^(3+)was studied,and the concentration of Cr^(3+),solution pH,pH of buffer solution and dosage of buffer solution were optimized.In Na_(2)HPO_(4)-C(OH)(COOH)(CH_(2)COOH)_(2)(citrate)buffer solution(pH=5.60),the concentration of Cr 3+is linearly related to the current in the range of 1.0~8.0μmol·L^(-1) with cyclic voltammetry.The modified electrode can be directly used for the determination of Cr^(3+)in waste water,and has strong anti-interference ability.
作者
李元胜
李娴
潘雨欣
董彦杰
LI Yuansheng;LI Xian;PAN Yuxin;DONG Yanjie(College of Chemistry and Chemical Engineering,Anqing Normal University,Anqing 246001,China)
出处
《鲁东大学学报(自然科学版)》
2024年第2期187-192,共6页
Journal of Ludong University:Natural Science Edition
基金
国家自然科学基金(21601002,B010303)
省部共建煤炭高效利用与绿色化工国家重点实验室开放课题(2019-KF-31)。
关键词
铬离子
钙钛矿材料
化学修饰电极
循环伏安法
chromium ion
perovskite material
chemical modified electrode
cyclic voltammetry