摘要
电解法制备NF_(3)的工艺可一步完成,有着过程简单且纯度高的优点。从阳极反应机理、阳极反应动力学和阳极极化三个方面综述了电解法制备NF_(3)的基础理论研究现状。针对当前阳极改性、电解液调控以及电解槽改造三个常见的优化方向进行了对比和总结。最后分析并探讨了今后的研究和发展方向。
The process of preparing NF_(3)by electrolysis can be completed in one step,which has the advantages of simple process and high purity.In this paper,the basic theoretical research of NF_(3)preparation by electrolysis was reviewed from three aspects:anodic reaction mechanism,anodic reaction kinetics and anodic polarization.A comparison and summary were made on the three common optimization directions of anode modification,electrolyte control and electrolytic cell modification,at present.Finally,the future research and development directions were discussed.
作者
张振
李梅
李贤武
酒坤
孙晓
李金勇
ZHANG Zhen;LI Mei;LI Xianwu;JIU Kun;SUN Xiao;LI Jinyong(Haohua Gas Co.,Ltd.,Luoyang 471012,China)
出处
《低温与特气》
CAS
2024年第2期1-6,17,共7页
Low Temperature and Specialty Gases
关键词
电解法
三氟化氮
阳极反应
电解液
电解槽
electrolysis method
nitrogen trifluoride
anodic reaction
electrolyte
electrolytic cell