摘要
Directly repairing end-of-life lithium-ion battery cathodes poses significant chal-lenges due to the diverse compositions of the wastes.Here,we propose a water-facilitated targeted repair strategy applicable to various end-of-life batches and cathodes.The process involves initiating structural repair and reconstruct-ing particle morphology in degraded LiMn_(2)O_(4)(LMO)through an additional thermal drive post-ambient water remanganization,achieving elemental repair.Compared to solid-phase repair,the resulting LMO material exhibits superior electrochemical and kinetic characteristics.The theoretical analysis highlights the impact of Mn defects on the structural stability and electron transfer rate of degraded materials.The propensity of Mn ions to diffuse within the Mn layer,specifically occupying the Mn 16d site instead of the Li 8a site,theoretically sup-ports the feasibility of ambient water remanganization.Moreover,this method proves effective in the relithiation of degraded layered cathode materials,yielding single crystals.By combining low energy consumption,environmental friendli-ness,and recyclability,our study proposes a sustainable approach to utilizing spent batteries.This strategy holds the potential to enable the industrial direct repair of deteriorated cathode materials.
出处
《SusMat》
SCIE
EI
2024年第2期28-40,共13页
可持续发展材料(英文)
基金
Beijing Natural Science Foundation,Grant/Award Number:Z220021
National Key R&D Program of China,Grant/Award Number:2022YFB3305400
National Natural Science Foundation of China,Grant/Award Numbers:22202011,52102207
Joint Funds of the National Natural Science Foundation of China,Grant/Award Number:U2130204
Beijing Outstanding Young Scientists Program,Grant/Award Number:BJJWZYJH01201910007023
Shandong Provincial Natural Science Foundation,Grant/Award Number:ZR2022QB056。