丁二烯定向合成C6高值化学品高效均相与多相催化体系构建

Construction of High Efficient Homogeneous and Heterogeneous Catalytic System for Butadiene Directed Synthesis of C6 High Value Chemicals

中国科学院兰州化学物理研究所、杭州师范大学与中海油北京材料院研究团队利用“异构体配体空间取向调控”策略,构建了适配直链中间产物过渡态的“催化口袋”,建立了丁二烯双氢氰化一步合成二腈高效催化新体系.

The research team from Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Hangzhou Normal University,and CNOOC Beijing Institute of Materials Research employed the“isomer ligand spatial orientation regulation”strategy and successfully established an efficient catalytic system for one-step synthesis of dinitrile from butadiene dihydrocyanide.