摘要
生物质基硬碳具有原材料资源丰富、可持续、成本低和储钠容量高等特点,是钠离子电池的理想负极材料。生物质基硬碳材料的微结构是决定钠离子存储性能的关键。本综述回顾了硬碳负极对钠离子存储机理的研究现状。从生物质原料的角度,分类总结了高性能生物质基硬碳材料的制备方法。探讨了生物质基硬碳结构的调控与钠离子存储性能提升的关系,对钠离子电池用生物质基硬碳负极材料的研究方向进行了展望。
Biomass-derived hard carbon has advantages of abundant raw-material resources,sustainability,low cost,and high sodium storage capacity,making it an ideal anode material for sodium-ion batteries(SIBs).The microstructure of biomass-derived hard carbon materials is one of the key factors to influence the sodium-ion storage performance.This review summarizes the research status on the mechanism of biomassderived hard carbon anodes for sodium-ion storage.Preparation methods for the high-performance biomassderived hard carbon anodes were summarized from the point of views of biomass sources.The relationship between structural regulation and the sodium-ion storage enhancement was discussed.Last but not the least,future research directions were prospected for developing high-performance biomass-derived hard carbon anodes for SIBs.
作者
吴芮瑶
欧阳丹丹
艾礼莉
刘岸杰
朱慧
高晓鑫
殷娇
WU Rui-Yao;OUYANG Dan-Dan;AI Li-Li;LIU An-Jie;ZHU Hui;GAO Xiao-Xin;YIN Jiao(College of Chemistry,Xinjiang University,Urumqi 830046,China;Xinjiang Technical Institute of Physics&Chemistry,Chinese Academy of Sciences,Urumqi 830011,China;Science&Technology Department of Xinjiang Uygur Autonomous Region,Urumqi 830011,China)
出处
《应用化学》
CAS
CSCD
北大核心
2024年第4期496-511,共16页
Chinese Journal of Applied Chemistry
基金
新疆维吾尔自治区重点研发项目(Nos.2022B01023,2022B02013,2022LQ01005)
中国科学院“西方之光”基金(No.2019-XBQNXZA-002)
中国科学院青年创新促进会支持(No.2019427)
国家自然科学基金青年基金(No.22205193)
国家重点研发计划项目(No.2023YFB4203703)
中央引导地方科技发展专项资金项目(No.ZYYD2023A06)
丝绸之路经济带创新驱动发展试验区、乌昌石国家自主创新示范区科技发展项目(No.2023LQ04002)。
关键词
硬碳
生物质
钠离子电池
负极材料
Hard carbon
Biomass
Sodium-ion battery
Anode material