一种含有长碳氟链的人造漆酚单体及其制备方法

Synthesis of an Artificial Urushiol with Perfluoroalkyl Chains

本文从廉价的大宗工业原料甲基丁香酚出发,通过可见光促进的末端烯烃官能团化反应,制备了含有长碳氟链的漆酚单体类似物。核磁分析结果表明其结构符合预期。这种“人造漆酚”单体具有与天然漆酚类似的疏水性,具有一定的应用潜力。

Starting from methyl eugenol,a cheap commercially available industrial raw material,to synthesizeurushiol monomer analogues containing long carbon fluorine chains were prepared by visible light promoted end olefin functionalization reaction.Its structure is confirmed by'H NMR spectrum.The assynthesized urushiol analogue bears similar hydrophobicity compared to natural urushiol and may be applicable in various fields.