摘要
以乙二醇(EG)为还原剂,通过波长为395 nm近紫外光和450、650 nm的可见光照射C_(60)及K_(2)[PtCl_(4)]混合液,制备了超细铂纳米颗粒(Pt/C_(60)-E)。利用X射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)、X射线光电子能谱(XPS)以及高分辨率透射电子显微镜(HR-TEM)等表征手段对Pt/C_(60)催化剂的组成及形貌进行了研究,结果表明,铂纳米颗粒在C_(60)表面分散良好,平均粒径约为2.6 nm。在催化p-NP还原实验中,在近紫外光(395 nm)照射下所制备催化剂(Pt/C_(60)-E3)表现出最高的催化活性,其速率常数k=0.12 min^(-1)。在催化剂循环实验中,多次循环催化剂仍具有较高的活性,实验证明光化学法对前驱体铂催化剂制备起到良好的作用。
This study focuses on synthesizing ultrafine platinum nanoparticles(Pt/C_(60)-E)by irradiating a mixture of C_(60) and K_(2)[PtCl_(4)]with ethylene glycol(EG)as the reducing agent.The process utilizes near-ultraviolet(UV)light at a wavelength of 395 nm,along with visible light at 450 and 650 nm.The composition and morphology of the Pt/C_(60) catalyst were investigated using characterization techniques including X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FT-IR),X-ray photoelectron spectroscopy(XPS),and high-resolution transmission electron microscopy(HR-TEM).The results revealed a well-dispersed distribution of Pt nanoparticles on the C_(60) surface,with an average particle size of about 2.6 nm.In the catalytic reduction experiments of p-NP,the Pt/C_(60)-E3 catalyst,prepared under near-ultraviolet irradiation(395 nm),exhibited superior catalytic activity,with a rate constant(k)of 0.12 min−1.Furthermore,in the catalyst cycling experiments,the catalysts remained highly active even after multiple cycles,demonstrating the effectiveness of the photochemical method in synthesizing precursor Pt catalysts.
作者
鲜亮
田小霞
马婧
李伟
XIAN Liang;TIAN Xiaoxia;MA Jing;LI Wei(School of Chemical Engineering,Northwest Minzu University,Lanzhou 730030,China;Key Laboratory for Utility of Environment-Friendly Composites and Biomass in Universities of Gansu Province,Lanzhou 730030,China)
出处
《中山大学学报(自然科学版)(中英文)》
CAS
CSCD
北大核心
2024年第3期137-146,共10页
Acta Scientiarum Naturalium Universitatis Sunyatseni
基金
Supported by National Natural Science Foundation of China(52167003)
Key Research and Development Projects in Gansu Province(21YF5WA064)。
关键词
超细铂纳米颗粒
富勒烯
光化学法
降解p-硝基苯酚
platinum ultrafine nanoparticles
fullerene
photochemical method
degradation of p-nitrophenol