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Eu掺杂ZnO多孔片状材料的制备及其降解印刷染料RhB

Preparation of Eu-doped ZnO Porous Sheet Material and study on Its Degradation of Printing Dye RhB
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摘要 采用常温络合-水解法构筑Eu掺杂Zn O多孔片状材料。通过SEM、TEM、XRD、EDS等表征手段证明稀土元素Eu成功掺杂到Zn O之中,Eu-Zn O的形貌为多孔片状结构。研究了Eu-Zn O多孔片状材料对染料的光催化性能。结果表明:该材料对Rh B具有较好的降解效率,降解效率高达99.2%,循环稳定性能高达98.3%,远大于商用Zn O的76.2%的降解效率和82.3%的循环稳定性能,由以上数据说明Eu-Zn O具有很好的光催化降解效率和循环稳定性能。其优异的光催化性能归因于稀土元素Eu掺杂和多孔片状结构。 Eu-doped ZnO porous sheet material was fabricated by room temperature complexation-hydrolysis method.SEM,TEM,XRD and EDS characterization proved that the rare earth element Eu was successfully doped into ZnO,and the morphology of EU-zno was porous and flake structure.In this paper,the photocatalytic properties of Eu-ZnO porous sheet materials for dyes were studied.The results showed that the degradation efficiency of Eu-ZnO was as high as 99.2%,and the cyclic stability was as high as 98.3%,which were much higher than the 76.2%degradation efficiency and 82.3% cyclic stability of commercial ZnO.The above data indicated that EU-zno had good photocatalytic degradation efficiency and cyclic stability.Its excellent photocatalytic performance was attributed to rare earth element Eu doping and porous sheet structure.
作者 吴娟 王晶 王刚 李丹婷 李英豪 王健俐 WU Juan;WANG Jing;WANG Gang;LI Dan-ting;LI Ying-hao;WANG Jian-li(School of Basic Sciences,Harbin University of Commerce,Harbin Heilongjiang 150028,China;Light Industry College,Harbin University of Commerce,Harbin Heilongjiang 150028,China)
出处 《当代化工》 CAS 2024年第4期764-768,共5页 Contemporary Chemical Industry
基金 国家自然科学基金项目(项目编号:52002099) 哈尔滨商业大学2022年校级教学改革与教学研究项目重点项目,德智融合下的《普通化学》“课程思政”教学的研究与实践(项目编号:HSDJY202206(Z)) 省自然科学基金项目(项目编号:18XN051)。
关键词 Eu-Zn O Rh B 常温络合-水解法 光催化 Eu-ZnO RhB Room temperature complexation-hydrolysis method Photocatalysis
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