摘要
针对目前厚浆型环氧树脂与厚浆环氧(HS)固化剂搭配使用的涂层室温实干时间过长(>6 h),不满足高固含压载舱涂料的室温实干时间(≤4 h)问题,采用了苯酚、多聚甲醛、硫脲、三乙烯四胺作为原料合成制备出一种酚醛胺加成固化剂,研究了其与HS固化剂按照质量比1∶0.5、1∶1、1∶2、1∶3、1∶4复配的涂层性能。结果表明,与HS固化剂1∶4质量比复配的涂层性能最佳,不仅可以缩短涂层室温实干时间至3.5 h,而且涂层还具有优异的力学性能和耐候性能,满足目前高固含压载舱涂料的性能需求。
Aiming at the problem that the room temperature drying time of the coating used with thick slurry epoxy resin and matching the thick-paste epoxy(HS)curing agent was too long(>6 h),which does not meet the room temperature drying time of the high solid content ballast tank coating(≤4 h),phenol,paraformaldehyde,thiourea and triethylene tetramine were used as raw materials to synthesize and prepare a phenolic amine addition curing agent.The properties of the composite coating with phenolic amine addition curing agent and HS curing agent at the mass ratios of 1∶0.5,1∶1,1∶2,1∶3 and 1∶4 were studied.The results showed that the composite coating with phenolic amine addition curing agent and HS curing agent at a mass ratio of 1∶4 had the best performance.It could not only shorten the drying time of the coating to 3.5 h at room temperature,but also had excellent mechanical properties and weather resistance,which could meet the performance requirements of the current high solid content ballast tank coating.
作者
饶兴兴
王木立
廉兵杰
王秀娟
王亚鑫
谭伟民
RAO Xing-xing;WANG Mu-li;LIAN Bin-jie;WANG Xiu-juan;WANG Ya-xin;TAN Wei-min(CNOOC Changzhou Paint and Coatings Industry Research Institute Limited Liability Company,Changzhou 213016,China;CNOOC Changzhou Environmental Protection Coating Limited Liability Company,Changzhou 213014,China)
出处
《热固性树脂》
CAS
CSCD
2024年第2期38-41,47,共5页
Thermosetting Resin
基金
国家重点研发计划(2020YFE0100100)
中国海洋石油集团前瞻项目(CNOOC-KJ-QZJC-CZY2020-02)
常州市应用基础研究计划(CJ20220197)。
关键词
环氧树脂
酚醛胺
多聚甲醛
固化剂
涂料
压载舱
实干时间
epoxy resin
phenolamine
paraformaldehyde
curing agent
coating
ballast tank
drying time