电化学介导的氧化羧化及二氧化碳还原羧化制备羧酸的研究进展

Research Progress in Preparation of Carboxylic Acids by Electrochemical Mediated Oxidative Carboxylation and Reductive Carboxylation of Carbon Dioxide

作为常见的一类重要化合物,羧酸被广泛应用于医药、农药和聚合物等领域,因此,探究高效且温和的羧酸合成方法具有重要意义.电化学合成羧酸因其环境友好、条件温和等优点,引起人们广泛关注.根据反应机理不同,主要从电化学氧化羧化、电化学二氧化碳还原羧化两方面出发,对电化学合成羧酸这一领域近年来的相关研究做了综述.

As a class of common and important compounds,carboxylic acids are widely used in areas of medicine,pesticides and polymers.Therefore,development of facile and efficient methods for the synthesis of carboxylic acids is of great significance.Electrochemical synthesis of carboxylic acids has attracted widespread attentions due to its environmentally friendly and mild conditions.This article mainly reviews the relevant research in electrochemical synthesis of carboxylic acids in recent years from two aspects:electrochemical oxidation for carboxylation and electrochemical reduction of carbon dioxide for carboxylation.