电化学硅基化反应的研究进展

Recent Advances in Electrochemical Silylation

有机硅化合物因其独特的物理化学性质,被广泛应用于合成、材料及医药等领域,受到了化学家们的广泛关注.因此,发展温和高效的合成方法构建有机硅化合物显得尤为重要.近年来,有机电化学得到了快速的发展,为合成有机硅化合物提供了一种全新的策略.其条件绿色温和、反应简单高效以及无需额外氧化还原试剂等优点,使得通过电化学硅基化反应合成有机硅化合物取得了长足的发展.根据硅前体和电化学反应类型的不同,主要从阴极还原硅基化反应和阳极氧化硅基化反应两个方面综述了电化学硅基化反应的研究进展.

Organosilicon compounds are widely applied in synthesis,materials,medicine and other fields due to their unique physical and chemical properties,and have attracted widespread attention from chemists.Therefore,it is particularly important to develop mild and efficient synthesis methods to construct organosilicon compounds.In recent years,the rapid development of electrochemistry provided a new strategy for the synthesis of organosilicon compounds.Due to its advantages of green and mild conditions,simple and efficient reactions,and no need for additional redox reagents,significant progress has been made in the synthesis of organosilicon compounds through electrochemical silylation reactions.The latest progress in electro-chemical silylation is mainly reviewed from two aspects:electrochemical silylation reactions via cathodic reduction,and electrochemical silylation reactions via anodic oxidation.