摘要
The present study reported the influence of heavy rare-earth elements(Gd and/or Dy)on Sm-Co-based melt-spun ribbons.Microstructure and magnetic properties of Sm-Co-based(Sm_(1-x)RE_(x)Co_(5))ternary and quaternary systems were investigated.The X-ray diffraction,Auger spectroscopy,scanning electron microscopy(SEM)and transmission electron microscopy(TEM)analyses reveal the presence of the 1:5H and 2:17R phases in the as-spun ribbons.A high-temperature magnetic measurement reports a Curie temperature(Tc)at~825 and~869 K in Sm0.6Gd0.4Co5(ribbon A)and Sm_(0.6)Gd_(0.3)Dy_(0.1)Co_(5)(ribbon B),respectively.A low-temperature magnetic measurement on Sm0.6Gd0.3Dy0.1Co5 ribbons exhibits a type-2 SR(spin reorientation)behaviour at~72 K,which arises due to the presence of the DyCo5 phase.Room temperature magnetic measurements reveal that overall magnetic measurement(OMP)is about 24 and 29.9 for ribbons A and B,respectively.Consequently,the comparative investigations profess that ribbon B shows better magnetic performance due to Dy addition with reduced grain size.This observation indicates that the Gd and Dy substituted Sm-Co magnet can be a potential magnet for high-temperature applications.
基金
Indian Institute of Technology Kharagpur,India。