摘要
The hydrosilylation of unsaturated carbon-carbon bonds is one of the most critical reactions in silicone industrial production.The homogeneous Speier's catalyst,Karstedt's catalyst,and other noble metal-based catalysts are widely used.However,simplifying the separation of the homogeneous catalyst from reaction products and reducing the high cost of precious metals is still challenging.This review describes the recent development of heterogeneous catalysts for alkene,alkyne,and allene hydrosilylations,which can effectively solve problems in homogeneous hydrosilylation.
基金
the financial support from the National Natural Science Foundation of China(No.22001227)
the Natural Science Foundation of Jiangsu Province(No.BK20200919)
the“Jiangsu Specially-Appointed Professor Plan”
the Priority Academic Program Development of Jiangsu Higher Education Institutions。