摘要
An inorganicDorganic hybrid crystalline material(SiMo_(12)O_(40))[Cu(2,2'-bipy)_(2)]_(2)·2H_(2)O(Complex 1,2,2'-bipy=2,2'-bipyridine)was synthesized for the first time by using 2,2'-bipy and transition metal copper to convert Waugh-type polyoxometalate[MnMo_(9)O_(3)_(2)]_(6-)into a Keggin polyoxometalate structure[SiMo_(12)O_(40)]^(4-)under hydrothermal conditions in glass vials.Single crystal tests and a series of characterizations were carried out on Complex 1.The structure of Complex 1 is composed of[SiMo_(12)O_(40)]^(4-)and[Cu^(Ⅱ)(2,2'-bipy)_(2)]^(2+).The five-coordinated Cu is connected to two 2,2'-bipy through CuDN bonds,forming an approximately square structure.Astonishingly,Complex 1 exhibited good photocatalytic performance for methylene blue degradation and electrocatalytic nitrite reduction properties simultaneously.
出处
《Rare Metals》
SCIE
EI
CAS
CSCD
2024年第5期2241-2250,共10页
稀有金属（英文版）
基金
supported by the National Natural Science Foundation of China(Nos.21971221,21401162 and 22201244)
Yangzhou University Interdisciplinary Research Foundation for Chemistry Discipline of Targeted Support(No.yzuxk202010)
?Qing Lan Project?in Colleges and Universities of Jiangsu Province,the High-Level Entrepreneurial and Innovative Talents Program of Yangzhou University and the Lvyangjinfeng Talent Program of Yangzhou,and China Postdoctoral Science Foundation(No.2022M722688)。
