摘要
铁基负极材料具有理论比容量高、反应电位低、环境友好等优势,成为锂离子电池领域的研究热点。然而,铁基负极材料在电池循环中存在体积膨胀大、离子/电子输运能力差等问题,较大地影响了铁基负极材料的广泛应用。基于这些问题,从纳米化构筑、碳材料复合和晶体结构调控等方面,综述了铁基负极材料的相关研究进展,以期为高性能铁基锂离子电池负极材料的研究和发展提供有效建议。
Iron-based anode materials,have the advantages of high theoretical specific capacity,low reaction potential and environmental friendliness,have become a research hotspot in the field of lithium-ion batteries.However,iron-based anode materials have the problems such as large volume expansion,poor electron and ionic conductivity in battery reactions,which greatly affects the wide application of iron-based anode materials.Based on these problems,the relevant research progress of iron-based anode materials from the aspects of nanoengineering,carbon materialsmodification and crystal structure regulation is reviewed.It will provide a valuable theoretical reference for the research and development of iron-based anode materials for high-performance lithium-ion batteries.
作者
张宗博
杨士祥
邱迪
商振坤
张帅国
ZHANG Zongbo;YANG Shixiang;QIU DI;SHANG Zhenkun;ZHANG Shuaiguo(School of Materials and Chemical Engineering,Henan University of Urban Construction,Pingdingshan 467000,China)
出处
《河南化工》
CAS
2024年第7期28-32,共5页
Henan Chemical Industry
基金
河南省科技攻关项目(232102231031)。
关键词
锂离子电池
铁基化合物
负极材料
碳复合材料
异质结构
lithium battery
iron-based compounds
electrodematerials
carbonmaterials
compositematerials