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S-Fe/C的制备及其对孔雀石绿和三氯乙烯的移除性能

Preparation of carbon-loaded sulfide nano-zero-valent iron and its removal properties against malachite green and trichloroethylene
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摘要 为了提高纳米零价铁对污染物的吸附和还原性能,采用气溶胶辅助制得碳载纳米零价铁(Fe/C),并通过对Fe/C硫化改性制备得到改性材料(S-Fe/C),采用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射分析(XRD)、X射线光电子能谱(XPS)等多种方法对材料进行表征,考察了S-Fe/C的材料特征。探究了该材料对孔雀石绿(MG)的吸附性能以及对三氯乙烯(TCE)的还原性能。结果表明,S-Fe/C对MG的吸附量达到1663 mg/g,对TCE 10 h去除率为85.57%,表明S-Fe/C具有良好的吸附性能和还原性能。 In order to improve the adsorption and reduction performance of zero-valent iron nanoparticles on pollutants,the carbon-loaded zero-valent iron nanoparticles(Fe/C)were prepared by aerosol-assisted fabrication,and the modified material(S-Fe/C)was prepared by sulfurizing and modifying Fe/C.The material characteristics were investigated by various methods,such as scanning electron microscope(SEM),transmission electron microscope(TEM),X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),etc.The material characteristics of S-Fe/C were also investigated,and the material characteristics of S-Fe/C were investigated.The adsorption properties of the material towards malachite green(MG)and the reduction properties towards trichloroethylene(TCE)were explored.The results showed that the adsorption of MG by S-Fe/C reached 1663 mg/g and the removal rate of TCE for 10 h was 85.57%,indicating that S-Fe/C has good adsorption and reduction properties.
作者 杨春林 占敬敬 YANG Chunlin;ZHAN Jingjing(School of Chemical Engineering,Ocean and Life Science,Dalian University of Technology,Panjin 124221,China)
出处 《应用化工》 CAS CSCD 北大核心 2024年第7期1505-1508,1514,共5页 Applied Chemical Industry
基金 国家自然科学基金面上项目(21876022)。
关键词 碳载硫化纳米零价铁 吸附 还原 孔雀石绿 三氯乙烯 S-Fe/C adsorption reduction malachite green trichloroethylene
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