摘要
面向污水厂二级出水深度脱氮的需求,构建了粉态硫自养反硝化膜生物反应器(p-SMBR),探究了水力停留时间(HRT)和膜通量对系统脱氮效果以及膜污染特性的影响。研究结果表明,在HRT为4 h时,p-SMBR表现出最佳的反硝化脱氮能力(98%),出水硝酸盐质量浓度<1 mg·L^(-1);同时可改善滤饼层结构,进而缓解膜污染,运行通量为20 L·(m^(2)·h)^(-1)时跨膜压增长速率仅为5.3 kPa·d^(-1)。微生物测序结果表明,Thermomonas和Thiomonas是反应器混合液中相对丰度最高的自养反硝化相关菌属,而Terrimonas和Flavobacterium则是滤饼层中造成膜污染的主要菌属。对p-SMBR的HRT和运行通量进行优化调控,可改变相关菌属的相对含量,进而起到同步高效脱氮与缓解膜污染的作用。
Facing the demand of deep nitrogen removal in the secondary effluent of wastewater plant,powdered sulfur autotrophic denitrification membrane bioreactor(p-SMBR)was constructed,and the influences of hydraulic retention time(HRT)and membrane flux on the nitrogen removal effect as well as membrane fouling characteristics of p-SMBR were investigated.The results showed that the p-SMBR exhibited the best denitrification denitrification capacity(98%)with effluent nitrate concentration lower than 1 mg·L^(−1) at a HRT of 4 h.Meanwhile,the structure of the filter cake layer was ameliorated,and in turn the membrane fouling was alleviated.At the operating flux of 20 L·(m^(2)·h)^(−1),the trans-membrane pressure growth rate was only 5.3 kPa·d^(−1).The results of microbial sequencing showed that Thermomonas and Thiomonas were the most relatively abundant autotrophic denitrification-associated genus in the mixture of p-SMBR,whereas Terrimonas and Flavobacterium were the main genus contributing to membrane fouling in the filter cake layer.Optimizing and regulation of the HRT and operating flux of p-SMBR can change the relative abundance of the relevant genus,which in turn serves to synchronouly realize an efficient nitrogen removal and membrane fouling mitigation.
作者
高珊珊
解冰瀚
耿明月
田家宇
GAO Shanshan;XIE Binghan;GENG Mingyue;TIAN Jiayu(School of Civil and Transportation Engineering,Hebei University of Technology,Tianjin 300401,China)
出处
《环境工程学报》
CAS
CSCD
北大核心
2024年第6期1604-1613,共10页
Chinese Journal of Environmental Engineering
基金
国家自然科学基金面上项目(52370035)
河北省自然科学基金项目(E2023202064)
河北工业大学本科教育教学改革研究与实践项目(220250)。
关键词
膜生物反应器
粉态硫自养反硝化
水力停留时间
膜通量
膜污染
membrane bioreactor
powder sulfur autotrophic denitrification
hydraulic retention time
membrane flux
membrane fouling