摘要
为了进一步阐明铝合金表面丙烯酸聚氨酯漆层的激光清洗机制,揭示扫描速度对激光除漆的影响规律,首先采用万能试验机测定了漆层强度极限,结合多种技术手段分析研究了单脉冲热-力耦合COMSOL仿真与清洗实验结果,探究了四种扫描速度(1000、900、800、700 mm/s)下除漆表面宏微观形貌及成分变化。结果显示:单脉冲除漆凹坑内存在明显分层与碎裂,除漆最大深度和宽度分别为34.3μm和125μm;漆层强度极限为2.68×10~7 Pa,与热应力仿真结果接近;随着扫描速度逐步降低,漆层去除深度不断增大,氧化膜逐步显现,面漆着色剂(β型铜酞菁)与漆层功能性氧化粒子的沉积量逐渐增加。研究表明:单脉冲激光除漆过程主要包括烧蚀、热应力和等离子体冲击三种除漆机制;随着扫描速度的逐渐降低,烧蚀除漆效果逐渐增强,等离子体冲击除漆效果逐步减弱,热应力除漆效果保持不变。
Objective Civil aircrafts operate under severe conditions,leading to issues such as peeling and cracking in the aircraft paint layer.This makes localized or comprehensive paint removal and surface maintenance pivotal during C-check or D-check procedures.Current paint removal methods,such as manual grinding and chemical stripping,are widely used.However,they have significant shortcomings.Manual grinding often lacks precision and can damage the aircraft surface,while chemical stripping is complicated and environmentally detrimental.These challenges hinder sustainable and efficient advancements in the civil aviation industry.Laser paint removal has emerged as a promising solution,offering high precision,reduced pollution,and automation possibilities.It is rapidly gaining global attention.However,a knowledge gap exists in understanding the exact mechanism of paint removal during laser ablation,particularly regarding the impacts of single-pulse thermal stress and plasma-induced removal.This study bridges this gap by first determining the vaporization point and strength limit of the paint layer.Then,single-pulse laser ablation simulations are compared with experimental results to better understand thermal stress paint removal during laser cleaning.This research sheds light on paint removal mechanisms and evaluates the impacts of varying scanning speeds on laser paint removal efficiency.Hence,the aim is to offer valuable insights and references for enhancing the use and development of laser paint removal techniques on civil aircraft skin.Methods In this study,the vaporization point and strength limit of the paint layer are first determined via thermogravimetry and stress-strain experiments.Subsequently,a finite element analysis of the single-pulse laser ablation-thermal stress paint removal process is conducted using the COMSOL software.Experiments on laser paint removal,both single-pulse and multi-pulse,at varying scanning speeds(ν=1000,900,800,and 700 mm/s),are performed on the composite paint system of the LY12 aluminum alloy substrate using nanosecond pulsed fiber lasers.Then,a white light interferometer(WLI)is employed to inspect and analyze the crater profile created by the single-pulse laser.An optical microscope(OM)is used to characterize the resulting surface and cross-sectional morphology from the multi-pulse line scanning laser paint removal.Additionally,a scanning electron microscope(SEM)and an energy-dispersive X-ray spectroscope(EDS)are utilized to analyze the microstructure and compositional changes on the cleaned surface after the paint is removed.Results and Discussions After the completion of single-pulse laser irradiation(t=200 ns),the paint ablation process does not cease.The accumulated heat causes the surface temperature of the residual paint layer to further increase until t=750 ns.When the temperature falls below its vaporization point,the ablation paint removal process concludes(Figs.6 and 7).At this moment,the action depth of thermal stress generated by the coupling of the temperature field on the surface of the residual paint layer gradually increases from the bottom to the edge of the crater,while the corresponding values progressively decrease(Fig.9).The maximum value(Fig.9,σ_(max)=2.7×10~7 Pa)approaches the strength limit of the paint layer[Fig.11(a),σ=2.68×10~7 Pa],leading to a U-shaped stress-damage zone on the surface of the residual paint layer(Fig.12).This results in physical damage,such as delamination and fragmentation of the residual paint layer(Fig.13).During the laser ablation process,both plasma impact and shielding effects coexist.The plasma impact causes the actual width of the ablated crater to be larger than the simulated results,while the shielding effect results in the experimental ablation depth of the crater being smaller than the simulated results(Fig.14).In the process of single-pulse laser paint removal,the ablation and plasma paint removal effects gradually intensify before the laser irradiation ends and then gradually weaken after the irradiation completes.However,the thermal stress paint removal effect remains unchanged(Fig.15).In the multi-pulse surface scanning laser paint removal experiments,the actual spot overlap rate is higher than the theoretical value(Fig.17),resulting in the removal depth of the paint layer being greater than that of the single-pulse results.As the scanning speed gradually reduces,the removal effect of the paint layer gradually enhances due to ablation,the plasma effect gradually weakens,and the depth of paint removal and the deposition amount ofβ-type copper phthalocyanine along with the functional oxidized particles gradually increase[Figs.16(a),(c),(e),and(g),and Table 10].Conclusions In this study,the single-pulse nanosecond laser thermo-mechanical coupling paint removal transient process is simulated using the COMSOL software.The results show that the behavior of ablative removal of paint layers does not finish at the end of one pulse cycle,and the heat accumulated on the cleaning surface extends the ablation process by 550 ns.The simulated thermal stress value is slightly larger than the experimentally determined tensile limit of the paint layer.This causes the residual paint layer on the cleaning surface to produce a delamination and cracking zone ranging from 0.6μm to 2.8μm.The laser ablation paint removal process triggers plasma impact and shielding.This makes the experimental crater paint removal width larger and the depth smaller than the simulation results.In the single pulse laser paint removal process,the ablation and plasma paint removal effects gradually intensify before the laser irradiation ends and then gradually weaken after the irradiation ends,but the thermal stress paint removal effect remains unchanged.As the scanning speed gradually decreases,the ablative paint removal effect strengthens,the plasma effect weakens,the thickness of the paint layer removal increases,and the amount of functionally oxidized particles deposited on the paint layer also increases.Whenν=1000 mm/s,the topcoat is partially removed and the primer is slightly damaged.The topcoat is removed cleanly,and the primer is partially removed whenν=900 mm/s.However,forν=800 mm/s and 700 mm/s,the area and depth of the residual primer continue to decrease with the reduction in the scanning speed,and the oxidized film is exposed.
作者
张天刚
李昱
邹俊豪
张志强
刘亚楠
Zhang Tiangang;Li Yu;Zou Junhao;Zhang Zhiqiang;Liu Yanan(School of Aviation Engineering,China Civil Aviation University,Tianjin 300300,China;School of Mechatronics Engineering,Harbin Institute of Technology,Harbin 150001,Heilongjiang,China)
出处
《中国激光》
EI
CAS
CSCD
北大核心
2024年第16期133-146,共14页
Chinese Journal of Lasers
基金
国家自然科学基金(U2033211)
中国民航大学研究生科研创新项目(2022YJS033)。
关键词
激光技术
激光清洗
铝合金
丙烯酸聚氨酯漆层
扫描速度
除漆机制
laser technique
laser cleaning
aluminium alloy
acrylic polyurethane lacquer coating
scanning speed
paint removal mechanism