摘要
Herein,we present a photoinduced,CeCl_(3)-catalyzed three-component decarboxylative reaction that couples carboxylic acids,alkenes and tert-butyl hydroperoxide for the formation of various organic peroxides.The ligand-to-metal charge transfer(LMCT)excitation mode allows the decarboxylative alkylation-peroxidation reaction to occur under mild conditions,and is well applicable to primary,secondary and tertiary carboxylic acids and styrene derivatives.
基金
supported by the National Natural Science Foundation of China(Nos.22071266,22201300).
