摘要
Stimuli-responsive coordination polymers(CPs)are among one of the most prolific research areas in developing the next-generation functional materials.Their capability of being accurately excited by particular external changes with pre-determined and observable/characterizable behaviors correspond,are the so called“stimuli”and“responsive”.Abundant types of CP compounds,especially metal-organic frameworks(MOFs),are of rocketing interest owing to their compositional diversity,structural tunability,and in essence their highly engineerable functionality.This present review is aimed to sketch several common types of stimulation and the corresponding responses for CPs,accompanied with the broad logic and mechanisms underneath.And further from the aspect of material revolution,some representative progresses together with the latest advances of CP-based materials in various fields are covered in attempt to display a broader picture towards the possible prospects of this topic.
基金
This work was supported by the National Key Research and Development Program of China(2022YFA1502901)
the National Natural Science Foundation of China[22035003,22371137 and 22201137]
the Nature Science Fund of Tianjin,China[19JCZDJC37200]
the Fundamental Research Funds for the Central Universities[63233040]
the Haihe Laboratory of Sustainable Chemical Transformations[YYJC202101]
the Science Foundation of State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter[20230029].