摘要
Lithium-sulfur batteries are considered potential high-energy-density candidates to replace current lithium-ion batteries.However,several problems remain to be solved,including low conductivity,huge volume change,and a severe shuttle effect on the cathode side,as well as inevitable lithium dendrites on the anode side.Rare earth compounds,which play vital roles in various industries,show latent capacity as cathode hosts or interlayers to tackle the inherent problems of lithium-sulfur batteries.However,the application of rare earth compounds in lithium-sulfur batteries has not been reviewed so far,despite they showing obvious advantages for tuning polysulfide retention and conversion.In this mini-review,we start by introducing the concept of lithium-sulfur batteries and providing background information on rare earth-based materials.In the main body,we explore rare earth compounds as cathode hosts or interlayers,then discuss various types of each.Finally,we offer an outlook on the existing challenges and possible opportunities for using rare earth compounds as cathode hosts or interlayers for lithium-sulfur batteries.
基金
The authors are grateful for financial support from National Natural Science Foundation of China(No.22002045,52025133)
The Research Fund of the State Key Laboratory of Solidification Processing,China(No.SKLSP202004)
Department of Education of Guangdong Province(No.2018KQNCX059 and 2020KTSCX033)
Guangdong Basic and Applied Basic Research Foundation(No.2023A1515030164)
2022 Guangdong-Hong Kong-Macao Greater Bay Area Exchange Programs of SCNU,Hong Kong Scholars Program 2022(Grant No.G-YZ5Y and XJ2022026).