摘要
To solve the electromagnetic pollution problem,the reasonable structure design and component control of the electromagnetic absorber is prominent.In this work,three-dimensional(3D)pyrolytic branched hollow architecture carbon PBHAC/MoS_(2)composites were prepared via a hydrothermal and calcination two-step strategy.The narrow-gap nano-size MoS_(2)acquired after vulcanization and micro-size 3D branched carbon skeleton PBHAC possess intensified conduction losses.Particularly,the presence of potential differences between different phases creates a space charge region at the heterogeneous interface,resulting in strong interfacial polarization.The resulting 3D branched hollow PBHAC/MoS_(2)composites exhibit optimized impedance matching and multiple loss mechanisms.Finally,the 3D branched hollow carbon PBHAC/MoS_(2)composites have the best electromagnetic wave(EMW)absorption performance.The minimum reflection loss(RLmin)is-57.8 dB at 1.93 mm and the maximum effective absorption bandwidth(EAB_(max))is 6.08 GHz at 2 mm,which indicates the excellent EMW absorption performance of the composites.Accordingly,this composite is expected to be a microwave absorber with the characteristics of“thin,light,wide,and strong”.
基金
financially supported by the National Natural Science Foundation of China(Nos.52377026,N52301192,No.52002196)
Natural Science Foundation of Shandong Province(Nos.ZR2019YQ24,No.ZR2020QF084)
Taishan Scholars and Young Experts Program of Shandong Province(No.tsqn202103057)
the Qingchuang Talents Induction Program of Shandong Higher Education Institution(Research and Innovation Team of Structural-Functional Polymer Composites)
Special Financial of Shandong Province(Structural Design of High-efficiency Electromagnetic Wave-absorbing Composite Materials and Construction of Shandong Provincial Talent Teams(No.37000022P990304116449)).