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CeO_(2)光催化原理及改性研究进展

Research Progress on the Principle and Modification of CeO_(2) Photocatalysis
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摘要 光催化技术是一种新兴的环境保护技术,可用于处理水和空气中的有机和无机污染物。CeO_(2)光催化剂由于其高稳定性和强光吸收能力而备受关注。但是CeO_(2)对自然可见光的吸收很弱,光生电子反应受限,在光催化中不能直接利用可见光促进电荷分离,这限制了催化活性和效率。本文主要从CeO_(2)自身的基本性能、结构和基本原理出发,综述了通过负载、掺杂及半导体复合等方法改性CeO_(2)光催化剂的研究进展,并展望了这一领域的发展前景。 Photocatalytic technology is an emerging environmental protection technology that can be used to treat organic and inorganic pollutants in water and air.CeO_(2)photocatalysts have attracted much attention due to their high stability and strong light-absorption.However pure CeO_(2)can absorb only a quite small part of natural visible light,restraining its photo-induced electron generation reaction.In photocatalysis conditions,CeO_(2)cannot directly utilize visible light to promote charge separation,thereby limiting its catalytic activity and efficiency.Starting from the basic properties,structure,and principles of CeO_(2),this review summarizes the modification of CeO_(2)using methods such as loading,doping,and semiconductor hybridization,and discusses the future development prospect of this field.
作者 莫日格吉乐 包莫日根 白璐 谢兵 于晓丽 曹鸿璋 赵丹蕾 赵斯琴 LIU Morigejile;BAO Morigen;BAI Lu;XIE Bing;YU Xiaoli;CAO Hongzhang;ZHAO Danlei;ZHAO Siqin(School of Chemistry and Environmental Sciences,Inner Mongolia Normal University,Hohhot 010022,China;Inner Mongolia Autonomous Region Key Laboratory of Environmental Chemistry,Hohhot 010022,China;China North Rare Earth(Group)High Tech Co.,Ltd.,Baotou 014010,Inner Mongolia,China;National Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization,Baotou 014060,Inner Mongolia,China;College of Chemistry and Chemical Engineering,Inner Mongolia University,Hohhot 010022,China)
出处 《材料导报》 EI CAS CSCD 北大核心 2024年第21期95-100,共6页 Materials Reports
基金 国家自然科学基金(22266025) 内蒙古自然科学联合基金项目(2022LHMS02001) 内蒙古师范大学基本科研业务费专项(2022JBTD009) 北方稀土项目(课题)技术开发基金(2022H2490)。
关键词 CeO_(2) 光催化 改性 负载 掺杂 半导体复合 cerium oxide photocatalysis modification load doping semiconductor hybridization
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