“沟脊”结构TPU纤维基高灵敏应变传感器的制备

Preparation of a highly sensitive strain sensor based on"furrow-ridge"structured TPU fibers

为了提高对微小形变的监测精度,增强柔性应变传感器的灵敏度,制备了一种“沟脊”结构热塑性聚氨酯(TPU)纤维基高灵敏应变传感器。首先在电场和金属电极片阵列接收装置的协同作用下,得到具有模量差异的“沟脊”结构TPU超细纤维基底,随后采用喷涂式层层沉积技术复合导电银层,得到“沟脊”结构TPU纤维基应变传感器。研究表明:“沟脊”结构使得纤维膜的拉伸强度、断裂伸长率提高至13.26 MPa和355.81%,灵敏度在各应变区间均获得数倍增长。“沟脊”结构纤维膜具有正交的纤维排列角度,该种结构不仅可以增强纤维膜的局部应变、诱导表面导电层材料形貌发生较大变化,而且独特的纤维转向将引导产生贯穿型裂纹,引起电阻的急剧增长,灵敏度系数最高可达151.36,同时具有100%的宽工作范围。“沟脊”结构TPU纤维基高灵敏应变传感器在智能可穿戴、医学诊断、人机交互等方面有广阔的应用前景。

With the development of the artificial intelligence,the demand for flexible electronic devices is constantly increasing.Flexible resistive strain sensors,with a simple structure and fabrication process,can convert external mechanical stimuli into electrical signals,and exhibit high stretchability and adaptability,leading to wide utilization in smart wearables,medical diagnostics,soft robotics,and other fields.Traditional resistive strain sensors usually employ flexible polymer films as their substrate,but their poor breathability and water permeability reduce comfort of wearing,resulting in redness and even allergic reactions.Electrospun ultrafine fibers,characterized by their rich porosity,lightness,thinness,softness,and good conformability,are an ideal flexible electronic platform.However,ultrafine fibers obtained through conventional spinning processes are usually randomly or unidirectionally arranged.Under low strain conditions,fiber sliding buffers most of the strain,resulting in minimal changes in the morphology of the conductive layer and limited sensitivity.This problem greatly compromises the monitoring accuracy of the sensor and reduces its ability to capture valuable but small deformations and provide feedback.To enhance the sensitivity of ultrafine fiber-based flexible strain sensors,a thermoplastic polyurethane(TPU)ultrafine fiber-based strain sensor with"furrow-ridge"structure was proposed.Firstly,a metal sheet array collector was designed to control the local fiber accumulation density and fiber alignment orientation under the driving force of the electric field,resulting in TPU ultrafine fiber substrate with a"furrow-ridge"structure.Subsequently,a highly sensitive flexible strain sensor was prepared by deposition of a brittle conductive silver(Ag)layer by using a fast and efficient spray coating technique.This method is simple and versatile,and can be used to prepare various electrospun fiber-based materials with a"furrow-ridge"structure,significantly enhancing sensitivity while maintaining a wide working range.It is found that the"furrow-ridge"structured ultrafine fiber substrate has orthogonal fiber alignment angles.This structure not only improves the tensile strength(13.26 MPa),elongation at break(355.81%),and elasticity(84.71%)of the fiber mat but also enhances local strain and induces significant changes in the morphology of the surface conductive layer material.Additionally,the unique fiber orientation guides the generation of cut-through cracks,leading to a sharp increase in electrical resistance and a significant improvement in sensitivity,with a maximum gauge factor reaching 151.36.The research can provide suggestions for the design and development of highly sensitive strain sensors and have broad prospects for applications in electronic skin,medical diagnostics,human-computer interaction,and other fields.