摘要
FeP/FeO was prepared on carbon cloth(CC)via hydrothermal method,heat treatment in air,and phosphorization in argon.FeP/FeO/CC presents a porous and loose morphology which is conducive to the exposure of active sites and the transfer of reactants.FeP/FeO/CC requires the low overpotentials of 257 and 117 mV(vs.reversible hydrogen electrode(RHE))to achieve the current density of 10 mA_·cm^(-2)for oxygen evolution reaction(OER)and hydrogen evolution reaction(HER)in alkaline KOH solution,respectively.The small Tafel slope values of 36.1 mV_·dec^(-1)(for OER)and 96.2 mV_·dec^(-1)(for HER)indicate that FeP/FeO/CC exhibits the fast electrocatalytic reactive kinetics for OER and HER.In particular,the reaction kinetics of FeP/FeO/CC accelerated with the progress of HER.The charge-transfer resistance(R_(ct))of FeP/FeO/CC is only 11Ω.Excellent bifunctional electrocatalytic performances of FeP/FeO/CC should be attributed to the porous morphology and the lower charge-transfer resistance.
基金
Funded by the Natural Science Foundation of Anhui Higher Education Institution of China(No.2023AH040160)
the Natural Science Foundation of Anhui Province(No.1808085QE126)
the Hefei Normal University High level Talent Research Startup Fund Project(No.2022rcjj55)
the Collaborative Innovation Project of Colleges and Universities in Anhui Province(No.GXXT-2021-091)。
