摘要
为解决传统合成氨催化剂制备复杂、反应速率低、资源浪费等问题,提出MgAl Ru-500R光热催化合成氨生产工艺。根据实验要求制备催化剂,从吸光度和宽光谱吸收性能两方面进行MgAl Ru-500R吸光度测试,分析常压条件下的光热催化合成氨性能,评估催化剂应用效果。结果表明,常压条件下,MgAl Ru-500R催化剂可发生合成氨反应,温度影响产氨速率,380℃时达到3.0 mmol/(g·h);温度一致时,催化剂在光热催化时的活性较纯热催化大幅提高;光的引入加速解离氮气分子,提高产氨速率。MgAl Ru-500R光热催化合成氨工艺应用效果良好,对氨合成产业发展起到推动作用。
To solve the problems of complex preparation,low reaction rate,and resource waste in traditional ammonia synthesis catalysts,the MgAlRu-500R photothermal catalytic ammonia production process is proposed.Prepare the catalyst according to the experimental requirements,conduct MgAlRu-500R absorbance testing from both absorbance and broad-spectrum absorption performance,analyze the performance of photothermal catalytic synthesis of ammonia under atmospheric pressure conditions,and evaluate the application effect of the catalyst.The results showed that under normal pressure,MgAlRu-500R catalyst can undergo ammonia synthesis reaction,and temperature affects the ammonia production rate,reaching 3.0 mmol/(g·h)at 380℃.When the temperature is consistent,the activity of the catalyst in photothermal catalysis is significantly improved compared to pure thermal catalysis.The introduction of light accelerates the dissociation of nitrogen molecules and increases the rate of ammonia production.The application effect of MgAlRu-500R photothermal catalytic synthesis of ammonia is good,which plays a promoting role in the development of ammonia synthesis industry.
作者
孙伟
Sun Wei(Shanxi Xingxin Safety Production Technology Service Co.,Ltd.,Taiyuan Shanxi 030008,China)
出处
《山西化工》
CAS
2024年第10期116-118,共3页
Shanxi Chemical Industry
关键词
光热催化剂
合成氨
吸收光谱测试
速率
photothermal catalyst
synthetic ammonia
absorption spectroscopy testing
rate