摘要
Two-dimensional(2D)materials have demonstrated promising prospects owing to their distinctive electronic properties and exceptional mechanical properties.Among them,2D superconductors with T_(c) above the boiling point of liquid nitrogen(77 K)will exhibit tremendous applicable value in the future.Here,we design two 2D superconductors Na(BC)_(2) and K(BC)_(2) with MgB2-like structures,which are theoretically predicted to host T_(c) as high as 99 and 102 K,respectively.The origin of such high T_(c) is ascribed to the presence of both𝜎-bonding bands and van Hove singularity at the Fermi level.Furthermore,T_(c) of Na(BC)_(2) is boosted up to 153K with a biaxial strain of 5%,which sets a new record among 2D superconductors.The predictions of Na(BC)_(2) and K(BC)_(2) open the door to explore 2D high-temperature superconductors and provide a potential future for developing new applications in 2D materials.
基金
supported by the National Natural Science Foundation of China(Grant Nos.12122405 and 12274169)
the National Key Research and Development Program of China(Grant Nos.2022YFA1402304 and 2023YFA1406200)
the Fundamental Research Funds for the Central Universities。
