摘要
高熵合金优异的物理、化学及力学性能,使其在航空、航天、海洋、核能、医疗、新能源等重大领域得到了广泛应用。高熵合金在储氢材料中极具发展潜力,但相关研究目前处于起步阶段,对储氢性能的研究也有限。结合储氢技术对高熵合金材料的需要,综述了目前关于高熵合金储氢性能的研究进展,对近年来国内外高熵合金储氢性能的研究成果进行了总结。研究发现,对高熵合金进行合金化处理可以显著提高储氢容量、改善吸/放氢动力学和循环稳定性等。下一步应深入探究高熵合金的吸/放氢机理,对比研究不同高熵合金储氢性能,并应用于实际的储氢系统进行工程实践。研究成果可为相关领域研究人员提供参考。
The excellent physical,chemical and mechanical properties of high-entropy alloys have led to their widespread application in major sectors such as aerospace,marine engineering,nuclear energy,medical and new energy sources.High-entropy alloys show great potential in hydrogen storage materials;however,the related research is still in its infancy,and studies on their hydrogen storage performance are limited.Taking into consideration the needs of hydrogen storage technology for high-entropy alloy materials,this paper summarizes the current research progress on hydrogen storage performance of high-entropy alloys,including recent research results from studies at home and abroad.Research shows that alloying treatment of high-entropy alloys can significantly increase hydrogen storage capacity,improve hydrogen absorption and desorption kinetics,and enhance cycle stability.Future research should focus on further exploring the hydrogen absorption and desorption mechanism of high-entropy alloys,comparing the hydrogen storage performance of different high-entropy alloys,and applying them in engineering practice on actual hydrogen storage system.This study can be used to provide reference for researchers in related fields.
作者
郭克星
曹光绪
席敏敏
高杰
GUO Kexing;CAO Guangxu;XI Minmin;GAO Jie(CNPC Baoji Petroleum Pipe Industry Co.,Ltd.,Baoji,Shaanxi,721008,China;Chinese National Engineering Research Center for Petroleum and Natural Gas Tubular Goods,Co.,Ltd.,Xi an,Shaanxi,710018 China;Shaanxi Special Equipment Inspection and Testing Institute,Xi an,Shaanxi,710000,China)
出处
《天然气与石油》
2024年第5期114-118,共5页
Natural Gas and Oil
基金
国家重点研发计划项目“高应变海洋管线管研制”(2018YFC0310300)
中国管线研究组织项目“X80级管线钢制管后强度变化规律研究”(CPRO2018NO3)
中国石油天然气股份有限公司科学研究与技术开发项目“煤炭地下气化关键技术研究与先导试验”(GF 2019E-25)
中国石油天然气股份有限公司科学研究与技术开发项目“二氧化碳规模化捕集、驱油与埋存全产业链关键技术研究及示范”(2021ZZ01)
中国石油天然气股份有限公司重大科技专项“高压储氢四型瓶关键材料及制备技术开发”[2021DJ5001(JT)]
中国石油天然气股份有限公司科学研究与技术开发项目“超临界二氧化碳长距离管道关键技术研究”(2021ZZ01)。
关键词
高熵合金
固态储氢
储氢性能
吸氢
脱氢
High-entropy alloy
Solid state hydrogen storage
Hydrogen storage performance
Hydrogen absorption
Hydrogen desorption