以乙醇为流变介质合成一水杨酸铜及结构分析

COPPER MONOSALICYLATE WAS SYNTHESIZED BY TAKINGALCOHOL AS RHEOLOGICAL MEDIUM AND ITS STRUCTURE ANALYSIS

以乙醇为流变介质合成了一水杨酸铜CuSal(Sal =o -OC6 H4 CO2 ) .用TG ,IR ,XRD和磁矩对其结构进行了表征 .配合物属于单斜晶系 ,其晶胞参数为a =10 .986 7(37) ,b=19.5 10 8(2 4 ) ,c =9.115 7(86 ) (10 - 10 m) ,β =10 4 .1,V =1895 .2 (77) (10 - 10 m) 3,Z =9,Dcalc=1.86 1g/cm3,Dexp=1.86 4g/cm3.结果表明 ,以乙醇和以水为流变介质得到的一水杨酸铜是组成相同。

Copper monosalicylate CuSal(Sal= o -OC 6H 4CO 2) was synthesized by taking alcohol as rheological medium.The structure was characterized by IR,TG, X -ray power diffraction and magnetic moment. XRD indicated the complex are monoclinic crystal system and the crystal cell parameters are a = 10.9867(37) , b =19.5108(24), c =9.1157 (86)(10 -10 m), β =104.1, V =1895.2(77) (10 -10 m) 3, Z =9, D calc =1.861g/cm 3, D exp =1.864 g/cm 3 .The experiment testifies that it is same in constitution and unlike in structure and that two copper monosalicylates were synthesized by taking alcohol and water as rheological medium.