摘要
我们曾报道了聚环氧氯丙烷键联的高分子钛络合物的合成及其催化活性,本文以聚(β-氯乙基缩水甘油醚)为载体,“一锅法”合成了几种高分子钛络合物:
With poly(β-chloroethyl glycidyl) as carrier, some new poly(β-chlo-roethyl glycidyl ether)-linked -Cp2TiCl2 complexes were synthesized by 'one pot' method. These products were analyzed and identified. The isomerization of safrole catalyzed by -Cp2TiCl2 was studied. It was proved by ESR that the titano-hydrogen derivatives of polymer-metallic complexes are mainly present in an unpolymeric form.
基金
国家自然科学基金
