摘要
利用多巴胺在溶液中自聚得到聚多巴胺(PDA)颗粒,然后将其作为填料加入聚偏氟乙烯(PVDF)中,采用溶液成膜法制备具有紫外线屏蔽功能的PDA/PVDF复合膜.通过傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)和紫外可见分光光度计(UV-Vis)对制备的PDA颗粒的结构、形貌以及吸光度进行表征,并且进一步利用X射线衍射仪(XRD)、差示扫描量热仪(DSC)、热失重分析仪(TGA)、接触角测量仪(CA)以及紫外老化箱等对PDA/PVDF复合膜的结构、热性能、润湿性能与紫外线屏蔽性能进行测试.结果表明,制备的PDA颗粒的粒径约为160 nm;掺杂PDA之后的PVDF膜的结晶度以及接触角均减小;并且PDA质量分数为5%时得到的PDA/PVDF复合膜在200~400 nm范围内的透过率均低于1%,能够吸收所有的紫外线,表现出优异的紫外线屏蔽功能.
Polydopamine(PDA)particles were fabricated via the self-polymerization of dopamine in the solution.Then PDA/PVDF(polyvinylidenefluoride)composite membranes with excellent ultraviolet(UV)shielding property were prepared through solution casting method using PDA particles as fillers.The chemical structure,morphology and absorbance of the as-prepared PDA particles were characterized by means of Fourier transform infrared spectroscopy(FTIR),scanning electron microscopy(SEM)and UV-Vis spectrophotometer.Furthermore,the structure,thermal property,wettability and UV shielding performance of the obtained PDA/PVDF composite membranes were confirmed by X-ray diffraction(XRD),differential scanning calorimetry(DSC),thermal gravimetric analyzer(TGA),water contact angle(CA)measurement and UV aging oven.The results displayed that the diameter of PDA particles were around 160 nm.The crystallinity and contact angle of the PVDF membranes became smaller after being modified with PDA particles.When the content of PDA was5%,the UV transmittance of the as-obtained PDA/PVDF film decreased to less than 1%in the wavelength range of 200—400 nm.Consequently,the composite film could block all of the UV light,indicating the excellent ultraviolet shielding property.
作者
熊征蓉
董莉
刘向东
杨宇明
XIONG Zhengrong;DONG Li;LIU Xiangdong;YANG Yuming(CAS Key Laboratory of High-Performance Synthetic Rubber and Its Composite Materials,Changchun Institute of Applied Chemistry,Changchun 130022,China;School of Applied Chemistry and Engineering,University of Science and Technology of China,Hefei 230026,China)
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2019年第4期849-854,共6页
Chemical Journal of Chinese Universities
关键词
聚偏氟乙烯
聚多巴胺
紫外线屏蔽
复合膜
Polyvinylidene fluoride
Polydopamine
Ultraviolet shielding
Composite membranes