化学动力学在无机化学中的若干应用——反应速率机理的探讨

A Preliminary Study on the Mechanism of the Chemical Reaction Rate-The Application of Chemical Kinetics to Inorganic Chemistry

本文就涉及无机化学中的动力学问题——反应速率机理,特别是氧化还原反应中“电子桥”催化机理,作了初步的探讨。导出的定量的速率公式,表述了反应速率与活化能间的关系。无疑,这对研究类似问题,具有一定的理论和实际意义。

This paper presents the author's preliminary study on kinetic pr -blems ot inorganic chemistry the mechanism of reaction rate, especially the catalytic mechamism of 'eletron-bridge' in redox reaction. The de-duced fomula indicates the relationship between the reaction rate and the activation energy. It is hoped that this paper will be of some help both theoratcally and practically to those who make. further study ni this field.