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Electrochemical behaviour of commercially pure titanium and Co-Cr alloy in Ringer's solution

Electrochemical behaviour of commercially pure titanium and Co-Cr alloy in Ringer's solution
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摘要 The electrochemical behaviors of commercially pure titanium (CP Ti) and Co-Cralloy in Ringer's solution have been investigated. The results indicate that the electric potentialof passive region for CP Ti is up to 3000 mV, and its passive current density is 3.078 μA/cm^2.The excellent corrosion resistance of CP Ti can be attributed to the formation of TiO_2 oxide film.The passive region of Co-Cr alloy is 770 mV, which is narrower than that of CP Ti. However, nohysteresis loops are found in the reverse scanning curves of Cu-Cr alloy. A complex oxide film ofCo_3O_4, Co_2O_3, and Cr_2O_3 formed on the surface provides Co-Cr alloy with a stableelectrochemistry property. The corrosion rates of the crevice samples increase with the pH value ofmedium decreasing. The electron probe microanalyzer (EPMA) analysis indicates that Ti in CP Ti andCo, Cr in Co-Cr alloy dissolve in crevice area due to the Sealed-Cell effect. The electrochemical behaviors of commercially pure titanium (CP Ti) and Co-Cralloy in Ringer's solution have been investigated. The results indicate that the electric potentialof passive region for CP Ti is up to 3000 mV, and its passive current density is 3.078 μA/cm^2.The excellent corrosion resistance of CP Ti can be attributed to the formation of TiO_2 oxide film.The passive region of Co-Cr alloy is 770 mV, which is narrower than that of CP Ti. However, nohysteresis loops are found in the reverse scanning curves of Cu-Cr alloy. A complex oxide film ofCo_3O_4, Co_2O_3, and Cr_2O_3 formed on the surface provides Co-Cr alloy with a stableelectrochemistry property. The corrosion rates of the crevice samples increase with the pH value ofmedium decreasing. The electron probe microanalyzer (EPMA) analysis indicates that Ti in CP Ti andCo, Cr in Co-Cr alloy dissolve in crevice area due to the Sealed-Cell effect.
出处 《Rare Metals》 SCIE EI CAS CSCD 2002年第4期266-270,共5页 稀有金属(英文版)
基金 This project is financially supported by the Natural Science Foundation of Liaoning Province (No.972210), China
关键词 ringer's solution biomedical material electrochemical behaviors ringer's solution biomedical material electrochemical behaviors
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  • 1梁成浩,防食技术,1988年,37卷,11期,679页
  • 2梁成浩,太阳能学报,1986年,7卷,3期,322页

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