KINETICS OF POLYMERIZATION OF METHYL METHACRYLATE INITIATED BY COPPER POLYPROPYLENE—BASED POLY（OXIME—IMIDODIACETATE）—SODIUM SULFITE SYSTEM

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摘要 The aqueous polymerization of methyl methacrylate intiated by copper polypropylene-based poly(oxime-imidodiacetate)(P-Cu)-sodium sulfite system has been investigated.The overall rate of polymerization(Rp) was found to be Rp=5.8×10^12e^-84.1KJ/RT[MMA]^1.4[P-Cu]^0[Na2SO3]^0.50 A mechanism of “coordination-proton transfer”for the production of initiating species was proposed and discussed.

作者 WUJinyuan YANGChaoxiong 等

机构地区 GuangzhouInstituteofChemistry

出处《Chinese Journal of Reactive Polymers》 1992年第2期97-103,共7页 中国反应性高分子（英文版）

关键词动力学聚合反应聚丙烯铜甲基丙烯酸甲酯聚(肟-亚氨双乙酸)-亚硫酸钠

分类号 O623.624.1 [理学—有机化学] O631.5 [理学—高分子化学]

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1吴锦远,杨义光,杨超雄.KINETICS OF POLYMERIZATION OF METHYL METHACRYLATE INITIATED BY COPPER POLYPROPYLENE-BASED POLYAMIDOXIME-SODIUM SULFITE SYSTEM~*[J].Chinese Journal of Polymer Science,1992,10(3):270-275.
2HUANG, Wei-Yuan WU, Fan-Hong HUANG, Bing-NanShanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China.The sulfinatodehalogenation of primary polyfluoroalkyl iodides by sodium sulfite[J].Chinese Journal of Chemistry,1994,12(6):549-551.
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Chinese Journal of Reactive Polymers

1992年第2期

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KINETICS OF POLYMERIZATION OF METHYL METHACRYLATE INITIATED BY COPPER POLYPROPYLENE—BASED POLY（OXIME—IMIDODIACETATE）—SODIUM SULFITE SYSTEM

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