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SYNTHESIS AND CHARACTERIZATION OF POLY(STYRENE - ETHYLENE OXIDE) DIBLOCK COPOLYMERS

SYNTHESIS AND CHARACTERIZATION OF POLY(STYRENE - ETHYLENE OXIDE) DIBLOCK COPOLYMERS
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摘要 Well - defined diblock copolymers Of styrene (St ) and ethylene oxide (EO )have been prepared by sequential living anionic polymerization of the twocomonomers in THF. Diphenyl methyl potassium has been used as initiator. Theblock copolymers were characterized in detail by methods Of size exclusion chromatography (SEC ) , 1H - Nab, FT - IR, dynamic mechanical analysis(Daal ) and WAXD. Well - defined diblock copolymers Of styrene (St ) and ethylene oxide (EO )have been prepared by sequential living anionic polymerization of the twocomonomers in THF. Diphenyl methyl potassium has been used as initiator. Theblock copolymers were characterized in detail by methods Of size exclusion chromatography (SEC ) , 1H - Nab, FT - IR, dynamic mechanical analysis(Daal ) and WAXD.
出处 《Chinese Journal of Reactive Polymers》 1998年第1期86-93,共8页 中国反应性高分子(英文版)
关键词 合成 聚(苯乙烯-乙撑氧)共聚物 阴离子聚合 Styrene - ethylene oxide, Diblock copolymer, Anionic polymerization
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