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Dendritic Macroinitiator for the Ring-Opening Polymerization of γ-Benzyl L-Glutamate N-Carboxyanhydride

Dendritic Macroinitiator for the Ring-Opening Polymerization of γ-Benzyl L-Glutamate N-Carboxyanhydride
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摘要 By using OH-terminated polyarylether dendrimer and N-Fmoc-glycine as raw materials, the dendritic polyarylether 2-aminoacetate (G3-NH2) was synthesized via two step reactions. G3-NH2 as a macroinitiator for the ring-opening polymerization of -benzyl L-glutamate N-carboxyanhydride was investigated. It is found that the resulting copolymers possessed relatively high molecular weight and narrow molecular weight distribution (1.12< Mw/Mn<1.28). By using OH-terminated polyarylether dendrimer and N-Fmoc-glycine as raw materials, the dendritic polyarylether 2-aminoacetate (G3-NH2) was synthesized via two step reactions. G3-NH2 as a macroinitiator for the ring-opening polymerization of -benzyl L-glutamate N-carboxyanhydride was investigated. It is found that the resulting copolymers possessed relatively high molecular weight and narrow molecular weight distribution (1.12< Mw/Mn<1.28).
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2002年第5期420-421,共2页 中国化学快报(英文版)
关键词 DENDRIMER MACROINITIATOR ring-opening polymerization polypeptide. Dendrimer, macroinitiator, ring-opening polymerization, polypeptide.
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