摘要
A new ET based cation radical salt, a-(ET)2C6H4(SO3)2 (ET = bis(ethylenedithio) tetrathiafulvalene) has been synthesized by oxidative electro-crystallization and the crystal structure determined to be in monoclinic system, P2/n space group. Its resistivity-temperature curve shows a semi-conductive behavior with a discontinuation at about 150K.
A new ET based cation radical salt, a-(ET)2C6H4(SO3)2 (ET = bis(ethylenedithio) tetrathiafulvalene) has been synthesized by oxidative electro-crystallization and the crystal structure determined to be in monoclinic system, P2/n space group. Its resistivity-temperature curve shows a semi-conductive behavior with a discontinuation at about 150K.
基金
This project was supported by a grant for the State Key Program of China and by the National Natural Science Foundation of China (No.20172034)
and also supported by the open laboratory of organic solid of Institute of Chemistry of the Chinese Academy
