摘要
The rate constant and kinetic isotopic effect(k H/k D) of the reduction of 2-bromo-1-phenylethylidenemalononitrile with NADH model were determined through NMR spectroscopy. The results were consistent with that the hydride transfer step of the reaction which was the rate-determining step, and were comparable to the results obtained through UV-Vis Spectroscopy reported previously.
The rate constant and kinetic isotopic effect(k H/k D) of the reduction of 2-bromo-1-phenylethylidenemalononitrile with NADH model were determined through NMR spectroscopy. The results were consistent with that the hydride transfer step of the reaction which was the rate-determining step, and were comparable to the results obtained through UV-Vis Spectroscopy reported previously.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2003年第1期73-75,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金 (批准号 :2 0 0 72 0 36
2 9832 0 40 )
中国科学技术大学青年基金资助
