污泥水热液化水相产物中氮元素变化规律的研究

Transformation Regularity of Nitrogen in Aqueous Product Derived from Hydrothermal Liquefaction of Sewage Sludge in Subcritical Water

亚临界水直接液化是实现污泥资源化的一种潜在手段.针对污泥亚临界水热液化水相产物中氮元素的变化规律进行了系统地研究.结果表明,在研究的反应温度和反应时间范围内,水相产物中总氮的质量浓度ρ(TN)在2 867.62~4 171.30mg·L-1之间变化,氮的主要存在形态为氨氮(NH+4-N)和有机氮(Org-N),其中NH+4-N占54.6%~90.7%,Org-N占7.4%~44.5%,ρ(NO-3-N)远远低于ρ(NH+4-N)及ρ(Org-N).反应温度是影响氮元素含量的重要因素,相同反应时间下ρ(TN)和ρ(Org-N)随反应温度的升高而降低.随反应时间的延长,ρ(TN)和ρ(Org-N)逐渐增加,而ρ(NH+4-N)则呈现出先增加,后平稳,再些许减少的趋势.

Hydrothermal liquefaction in subcritical water is a potential way to treat sewage sludge as a resource rather than a waste.This study focused on the transformation regularity of nitrogen in aqueous product which was derived from hydrothermal liquefaction of sewage sludge under different operating conditions. Results showed,within the studied temperature scope and time span,the concentration of total nitrogen( TN) fluctuated in the range of 2 867. 62mg·L- 1to 4 171. 30 mg·L- 1. The two major exiting formation of nitrogen in aqueous product was ammonia nitrogen( NH+4-N) and organic nitrogen( Org-N). NH+4-N possessed 54. 6%-90. 7% of TN,while Org-N possessed 7. 4%-44. 5%. The concentration of nitrate nitrogen( NO-3-N) was far more less than NH+4-N and Org-N.Temperature had a great influence on the transformation regularity of nitrogen. Both the concentration of TN and Org-N increased accordingly to the increase of reaction temperature. With the reaction time prolonging,the concentration of TN and Org-N increased,while the concentration of NH+4-N increased first,then became stationary,and then decreased slightly.